Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Identification product name sodium ethoxide, 21% ww in. Sodium ethoxide is an organic monosodium salt that has ethoxide as the counterion. Well, this sodium ethoxide chemical is very dangerous for human health when it comes to contact with your skin as well as eyes. Sodium ethoxide, 95% ch3ch2ona sodium ethylate sigma. Find msds or sds, a coa, data sheets and more information. Suppply high purity sodium ethoxide cas 141526 powder and solution sodium ethoxide ethanol solution 1.
The resulting solution, which is colorless, is often used as a source of sodium methoxide, but the pure material can be isolated by evaporation followed by heating to remove residual methanol. Skin contact wash off immediately with plenty of water for at least 15 minutes. Ethoxide and the malonate anionare about equal in basicity, 56 but ethoxide is a much harderbase. Ac168590000, ac168590010, ac168590025, ac168590050, ac168592500, ac168595000 ac168595000 synonyms.
Reaction of 2bromopropane with ethoxide gives primarily elimination, but similar reaction with the malonate anion gives the substitution product 27. Contaminated clothing should be removed and washed before reuse. Sodium ethoxide 20% solution in ethanol for synthesis find msds or sds, a coa, data sheets and more information. One reagent lane fair lawn, nj 07410 for information in north america. Sciencemadness discussion board sodium ethoxide with. Msds contains all of the information required by those regulations. Handling and storage avoid generation or accumulation of dusts. S sodium methoxide maritime transport imdg icaoiata class 4. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. The addition rate is adjusted so that the reaction does not become.
Safety data sheet of 6 infosafe no 1ch6f issue date. Intermediate for phenylbutazone, piroxicam,and so on. Aks741 sodium ethoxide, 21% in ethanol sodium ethoxide, 21% in ethanol safety data sheet aks741 date of issue. Application sodium ethoxide may be used as a base for the palladium catalyzed crosscoupling of aryl halides and alkenylboranes to. Sodium ethoxide 141 526 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Process simulation and technoeconomic analysis of the. Find product specific information including properties, cas, msds, protocols and references. Canadian ingredient disclosure list section 16 additional information msds creation date. The sodium ethoxide which is mixed in the solution ethanol will be colorless. Sds of sodium ethoxide, safety data sheets, cas 141526. Identification of the substancemixture and of the companyundertaking. It is considered as a strong base which can be synthesized by chemically reacting sodium hydroxide or sodium metal with ethyl alcohol. Sodium ethoxide, 21% in ethanol safety data sheet aks741. If the starting material is an ethyl ester, transesterification is irrelevant since the product is identical to the starting material.
Material safety data sheet section 1 1bromopentane 1 chemical product and company identification msds name. Sodium ethoxide 141526 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. For this reason, the conjugate sodium alkoxide base of the alcohol formed e. In mixed claisen condensations, a nonnucleophilic base such as lithium diisopropylamide, or lda, may be used, since only one compound is. To the clear solution is added slowly 685 gm of nbutyl bromide. Sodium ethoxide, 21% in ethanol revision date 19jan2018 attendance. Application of skinprotective barrier cream is recommended. Sigmaaldrich offers sigmaaldrich71210, sodium ethoxide for your research needs. This sodium ethoxide chemical, when mixed with water, that reacts to produce ethyl alcohol and ethanol. The worldwide increase in biodiesel production has created a major market for sodium methoxide, as a catalyst in the transesterification of vegetable oils. For methanol, it is easier to get close, since the initial methanol can be obtained nearly anhydrous, so there is only 1 molar equivalent of water in the solution, whereas ethanol containing 5% water has a large amount more water than that.
The reaction is so exothermic that ignition is possible. Identification product name sodium ethoxide, 21% ww in ethanol cat no. In general, hard bases give elimination and soft bases give substitution, but the gegenion has a. Safety data sheet creation date 09sep2009 revision date 22feb2018 revision number 1 1. A sodium ethoxide solution freshly prepared from 2. Safety data sheet northwest missouri state university. Ethoxide definition and meaning collins english dictionary. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Sodium ethoxide c2h5ona or c2h5nao cid 2723922 structure, chemical names, physical and chemical properties, classification, patents, literature. Sodium ethoxide msds material safety data sheet or sds, coa and coq, dossiers, brochures and other available documents.
Sodium ethoxide is an alkoxide salt mainly used as a strong base in organic reactions such as deprotonation, dehydration and dehalogenation. Identification of the substancemixture and of the companyundertaking 1. The number of electrons in each of sodium s shells is 2, 8, 1 and its electron configuration is ne 3s 1. Concerning your issue about the solubility of sodium methoxide with hexane. L83 synonyms no information available recommended use laboratory chemicals. Firstaid measures general advice show this safety data sheet to the doctor in attendance. Sodium ethoxide is the organic compound which dissolves in polar solvents such as ethanol. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Sodium methoxide is prepared by treating methanol with sodium.